Refinery Hydrotreater Heat Exchanger Retube — 321 & 2205 U-Tubes


Project Background
A major refinery in Saudi Arabia operates a naphtha hydrotreating unit where the feed/effluent heat exchanger originally used carbon steel tube bundles. After 5 years of service at 350°C in H₂S-rich environment, severe sulfidic corrosion caused tube wall thinning exceeding 0.3 mm/year. During a planned 45-day shutdown window, the owner needed complete retubing of 4 heat exchangers with upgraded materials to extend run length between turnarounds.
Technical Specifications
| Grade | ASTM A213 TP321 Seamless U-Tubes; UNS S32205 Seamless Pipes |
| Size Range | OD 19.05 – 38.1 mm (3/4" – 1-1/2"), multiple U-bend radii |
| Standards | ASTM A213, TEMA Class R, API 660, NACE MR0103 |
| NDE Requirements | Post-bend solution anneal + 100% Eddy Current + per-tube hydro (1.5× design P) |
The Challenge
U-tube bending introduces cold work residual stresses and sensitization risk in stainless steels. If not properly post-bend heat treated, this leads to stress corrosion cracking in H₂S service and reduced intergranular corrosion resistance — both unacceptable for refinery heat exchanger reliability.
TOKO TECH Solution
TOKO TECH performed secondary solution annealing (940°C ± 10°C / rapid cooling) on all 321 U-tubes after bending to eliminate cold work residual stresses and restore intergranular corrosion resistance. For the high-temperature H₂S section, 2205 duplex tubes were supplied, leveraging the duplex microstructure's superior resistance to stress corrosion cracking and significantly increasing operational safety margins.
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